Biogenic magnetite, detrital hematite, and relative paleointensity in Quaternary sediments from the Southwest Iberian Margin

<p>Magnetic properties of late Quaternary sediments on the SW Iberian Margin are dominated by bacterial magnetite, observed by transmission electron microscopy (TEM), with contributions from detrital titanomagnetite and hematite. Reactive hematite, together with low organic matter concentrations and the lack of sulfate reduction, lead to dissimilatory iron reduction and availability of Fe(II) for abundant magnetotactic bacteria. Magnetite grain-size proxies (<span class="mathmlsrc" id="mmlsi1"><span class="formulatext stixSupport mathImg" data-mathurl="/science?_ob=MathURL\&amp;_method=retrieve\&amp;_eid=1-s2.0-S0012821X13003427\&amp;_mathId=si1.gif\&amp;_user=111111111\&amp;_pii=S0012821X13003427\&amp;_rdoc=1\&amp;_issn=0012821X\&amp;md5=046121796546b530497c76d8438d7d08" title="Click to view the MathML source">κ_ARM/κ</span></span> and ARM/IRM) and S-ratios (sensitive to hematite) vary on stadial/interstadial timescales, contain orbital power, and mimic planktic <span class="mathmlsrc" id="mmlsi2"><span class="formulatext stixSupport mathImg" data-mathurl="/science?_ob=MathURL\&amp;_method=retrieve\&amp;_eid=1-s2.0-S0012821X13003427\&amp;_mathId=si2.gif\&amp;_user=111111111\&amp;_pii=S0012821X13003427\&amp;_rdoc=1\&amp;_issn=0012821X\&amp;md5=55b728104bfeae2ca4a6eb374a62d105" title="Click to view the MathML source">δ¹⁸O</span></span>. The detrital/biogenic magnetite ratio and hematite concentration are greater during stadials and glacial isotopic stages, reflecting increased detrital (magnetite) input during times of lowered sea level, coinciding with atmospheric conditions favoring hematitic dust supply. Magnetic susceptibility, on the other hand, has a very different response being sensitive to coarse detrital multidomain (MD) magnetite associated with ice-rafted debris (IRD). High susceptibility and/or magnetic grain-size coarsening, mark Heinrich stadials (HS), particularly HS2, HS3, HS4, HS5, HS6 and HS7, as well as older Heinrich-like detrital layers, indicating the sensitivity of this region to fluctuations in the position of the polar front. Relative paleointensity (RPI) records have well-constrained age models based on planktic <span class="mathmlsrc" id="mmlsi3"><span class="formulatext stixSupport mathImg" data-mathurl="/science?_ob=MathURL\&amp;_method=retrieve\&amp;_eid=1-s2.0-S0012821X13003427\&amp;_mathId=si3.gif\&amp;_user=111111111\&amp;_pii=S0012821X13003427\&amp;_rdoc=1\&amp;_issn=0012821X\&amp;md5=aeb3e2698dce7f3c18b7cdacf68cc8dd" title="Click to view the MathML source">δ¹⁸O</span><span class="mathContainer hidden"><span class="mathCode">δ18O</span></span></span> correlation to ice-core chronologies, however, they differ from reference records (e.g. PISO) particularly in the vicinity of glacial maxima, mainly due to inefficient normalization of RPI records in intervals of enhanced hematite input.</p>